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Journal of Coordination Chemistry Volume 73, 2020 - Issue 17-19
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Original Articles

Zinc(II) mononuclear complexes with Schiff base derivatives of 2-aminofluorene. Synthesis, structural characterization, and optical properties

Marianta StrinoiuInorganic Chemistry Department, Faculty of Chemistry, University of Bucharest, Bucharest, RomaniaView further author information
,
Mihai RăducăInorganic Chemistry Department, Faculty of Chemistry, University of Bucharest, Bucharest, RomaniaView further author information
&
Augustin M. MădălanInorganic Chemistry Department, Faculty of Chemistry, University of Bucharest, Bucharest, RomaniaCorrespondence[email protected]
ORCID Iconhttps://orcid.org/0000-0002-2275-5004View further author information
ORCID Icon
Pages 2786-2800 | Received 03 Aug 2020, Accepted 11 Sep 2020, Published online: 14 Oct 2020
 
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Abstract

Three Schiff base ligands derived from 2-aminofluorene and 3-methoxysalicylaldehyde (HL1), 3-ethoxysalicylaldehyde (HL2), or 2-formyl-6-hydroxymethyl-p-cresol (HL3) were synthesized and structurally characterized by X-ray diffraction on single crystals. The mononuclear complexes [Zn(L1)2] (4), [Zn(L2)2] (5), [Zn(L3)2]·CHCl3 (6a), and [Zn(L3)2] (6b) containing the monoanionic form of these ligands were obtained and structurally characterized. Luminescent properties of the ligands and complexes were investigated in solid-state.

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Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

Financial support from University of Bucharest (project 680/2014) is gratefully acknowledged.

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