Figures & data
Figure 1. Crystal structure of the PrIII complex [Pr2L6(H2O)2]n (symmetry code: *1 − X, 1 − Y, 1 − Z; #1 − X, −Y, 1 − Z; ^+X, 1 + Y, +Z). Hydrogen atoms were omitted for clarity.
![Figure 1. Crystal structure of the PrIII complex [Pr2L6(H2O)2]n (symmetry code: *1 − X, 1 − Y, 1 − Z; #1 − X, −Y, 1 − Z; ^+X, 1 + Y, +Z). Hydrogen atoms were omitted for clarity.](/cms/asset/6c4341d6-e2d8-49b6-bf6b-dbdf472097f2/gcoo_a_2384711_f0001_c.jpg)
Table 1. Crystal data and structural refinement for the reported PrIV complex, as a PrIII [Pr2L6(H2O)2]n complex and the reported EuIII complex.
Figure 2. H-Bond formation from O10 of coordinated water to two neighboring oxygen atoms. H10B–O6& (−x, 1 − y, 1 − z) 1.895(4) Å; H10A–O3$ (1/2 − x, y − 1/2, 1/2 − z 1.851(4) Å. O10–H10B–O6& 171.7(3)°, O10–H10A–O3$ 158.3(3)°.
![Figure 2. H-Bond formation from O10 of coordinated water to two neighboring oxygen atoms. H10B–O6& (−x, 1 − y, 1 − z) 1.895(4) Å; H10A–O3$ (1/2 − x, y − 1/2, 1/2 − z 1.851(4) Å. O10–H10B–O6& 171.7(3)°, O10–H10A–O3$ 158.3(3)°.](/cms/asset/a17bacc4-673c-4825-8872-f302a28b0910/gcoo_a_2384711_f0002_c.jpg)
Table 2. Bond lengths (Å) for the reported PrIV complex, as a PrIII complex [Pr2L6(H2O)2]n and the reported EuIII complex.