The effect of static disorder on pressure-induced phase transitions and amorphization in α-quartz-type solid solutions

Abstract

The high-pressure stability of α-quartz-type materials is of considerable interest for materials (piezoelectrics etc.) and Earth science. Representative compositions of two α-quartz type solid solutions SiO₂–PON and AlPO₄–GaPO₄ were studied at high pressure by X-ray diffraction. These materials exhibit distinct high pressure behaviour as the diffraction lines of α-quartz-type Si_0.56P_0.44O_1.56N_0.44 were found to decrease in intensity above 23 GPa with the pattern becoming completely featureless above 40 GPa, whereas Al_0.30Ga_0.70PO₄ transforms to a poorly-crystallised phase above 12 GPa. This difference in behaviour can be linked to the initial degree of positional disorder in the two solid solutions. A highly disordered, possibly amorphous, phase is favoured in the SiO₂–PON system, in which positional disorder is present on all cation and anion sites. In contrast, disorder affects only ½ of the cation sites in the AlPO₄–GaPO₄ system. A high degree of disorder, particularly on the site occupied by phosphorus, plays a role in inhibiting the formation of ordered phases with increased cation coordination.

Keywords:

• Quartz
• High pressure
• Amorphization
• Piezoelectricity

Acknowledgements

We would like to thank C. Chateau and G. Fraysse for synthesising the Si_0.56P_0.44O_1.56N_0.44 and Al_0.3Ga_0.7PO₄ samples, respectively and A. S. Pereira for useful discussions.