Equilibrium, thermodynamics and kinetics study on Au(III) extraction by gemini surfactant with different spacer length

ABSTRACT

The effect of spacer lengths of imidazolium gemini surfactant [C₁₄-n-C₁₄im]Br₂ (n = 2, 4, 6) on the equilibrium, thermodynamics and kinetics of Au(III) extraction from hydrochloric acid medium were investigated in this article. The thermodynamic parameters, including the changes in enthalpy (ΔH*), entropy (ΔS*) and Gibbs free energy (ΔG*) were determined. The values of ΔH* demonstrated that the extraction of Au(III) by [C₁₄-n-C₁₄im]Br₂ was endothermic at first and exothermic at last. The kinetics study found that extraction rate became faster when the spacer lengths were increased. Moreover, kinetics results demonstrated that the diffusion is the controlling step, and the mass transfer coefficients of Au(III) in the investigated systems indicated that the resistance of mass transfer was smaller when the spacer lengths was longer. The studies of interfacial tension further confirmed the better extractability of [C₁₄-n-C₁₄im]Br₂ with longer spacer lengths. Our results reveal efficient and sustainable gold separation.

KEYWORDS:

• Gold extraction
• gemini surfactant
• spacer lengths
• thermodynamics
• kinetics

Supplementary material

Supplemental data for this article can be accessed here.

Acknowledgments

We gratefully acknowledge the financial support from the National Nature Science Foundation of China (21476129) and Young Scholars Program of Shandong University (2016WLJH20).

Additional information

Funding

This work was supported by the Young Scholars Program of Shandong University [2016WLJH20];National Nature Science Foundation of China [21476129].