Shear bond strength of PEEK and PEEK-30GF cemented to zirconia or titanium substrates

Abstract

Objectives: The aim of this study was to evaluate the use of dual-cure resin cement to promote the bonding between a veneering PEEK and zirconia or titanium surfaces.

Materials and methods: The surface of titanium and sintered zirconia disks were gritblasted, ultra-sonically cleaned in distilled water, and dryed by oil-free air. Then, a adhesive system was applied on the clean and dry surfaces. Disks of PEEK or 30% glass-reinforced PEEK were cut from a rod and their surface were acid etched and therefore the PEEK roughness was analysed using a contact profilometer. A resin cement was then applied between the substrates and the veneering PEEK and light cured for 4 Shear bond strength tests were performed on PEEK-cement to zirconia or titanium interfaces. Scanning electron microscopy (SEM) analyses were performed to evaluate the samples surface, interface and failure mode.

Results: Surface treatment with acid etching decreased the average roughness of PEEK-based surfaces. oMicroscopic analyses by SEM revealed morphological aspects of a poor bonding between the resin-based cement and PEEK. Those aspects could be confirmed by the low mean values in shear bond strength. The fracture analysis showed that the main failure mode was adhesive, which explain the low values of shear bond strength.

Conclusion: PEEK is a promising material for dental applications. However, significant improvements on surface modifications and in chemical composition of the cement are still required for dental applications involving cementation of PEEK or PEEK-30GF to zirconia or titanium concerning a desirable long-term clinical performance of prosthetic structures.

Keywords:

• PEEK
• PEEK-30GF
• zirconia
• titanium
• dual-cure resin cement
• shear bond strength

Acknowledgments

The authors would like to thank FGM company (FGM Dental Products Ltda, Joinville, SC/Brazil) for supplying free of charge the resin Allcem CORE used in this research. This study was supported by FCT-Portugal (UID/EEA/04436/2013, NORTE-01-0145-FEDER-000018 – HAMaBICo, PTDC/EME-EME/31035/2017-LaserMULTICER) and CNPq-Brazil (PVE/CAPES/CNPq/407035/2013-3).

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

This study was supported by FCT-Portugal (UID/EEA/04436/2013, NORTE-01-0145-FEDER-000018 – HAMaBICo, FCT/02/SAICT/2017/3103-LaserMULTICER) and CNPq-Brazil (PVE/CAPES/CNPq/407035/2013-3).