1-(2-Hydroxyethyl)-2-imidazolidinone as corrosion inhibitor of mild steel in 0.5 M HCl solution: thermodynamic, electrochemical and theoretical studies

Abstract

The inhibition effect of 1-(2-Hydroxyethyl)-2-imidazolidinone (2-HEI) on mild steel (MS) corrosion in 0.5 M HCl solution was investigated at different inhibitor concentration and temperature by electrochemical experiments, such as linear polarization resistance (LPR), electrochemical impedance spectroscopy (EIS), potentiodynamic polarization and quantum chemical calculations. The inhibitor adsorption process on mild steel in 0.5 M HCl system was studied at different temperatures (20 °C–50 °C). Furthermore, the surface morphology of MS was also investigated with SEM in the absence and the presence of inhibitor. The adsorption of 1-(2-Hydroxyethyl)-2-imidazolidinone on MS surface is an exothermic process and this process obeys the Langmuir adsorption isotherm. The Quantum chemical findings are good agreed with the empirical data.

Keywords:

• Interfaces
• electrochemical techniques
• corrosion inhibitor
• SEM
• quantum chemical calculation
• adsorption

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

This study is supported by a grant from Scientific Research Projects Committee of Çukurova University and Mardin Artuklu University (MAÜ-BAP-16-SYO-06).