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Journal of Dispersion Science and Technology Volume 31, 2010 - Issue 8
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Original Articles

Supramolecular Assemblies and Self-Sorting of a Series of Cu(II)-Coordinated Schiff Bases Complexes at the Air/Water Interface

Tifeng Jiao Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, P.R. ChinaCorrespondence[email protected]
,
Juan Zhou Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, P.R. China
,
Minghua Liu Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface Science, Institute of Chemistry, CAS, Beijing, P.R. China
,
Sufeng Wang Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, P.R. China
,
Jingxin Zhou Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, P.R. China
&
Feihu Zhang Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, P.R. China
Pages 1120-1127 | Received 04 Mar 2009, Accepted 01 Apr 2009, Published online: 27 Jul 2010
 
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Abstract

A series of Cu(II)-coordinated Schiff bases complexes were synthesized and their supramolecular assemblies at the air/water interface were investigated. These complexes can form stable monolayer or multilayer films at the air/water interface, which represent discrete change of morphology and spectra, depending on the chosen coordinating modes. In addition, narcissistic self-sorting appears when the mixtures of the binary or ternary complexes were characterized at the air/water interface, demonstrating the spontaneous high affinity of molecules for themselves.

This work was financially supported by the National Natural Science Foundation of China (20903078 40671001, and 40830746), the Natural Science Foundation of Hebei Province (B2009000347), Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (CPRC020), and Scientific Research Plan of the Education Department of Hebei Province (Z2009146). F. Z. is thankful to the Undergraduate Innovational Experimentation Program of Yanshan University (CXCY0810Y) for their financial support.

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