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Journal of Dispersion Science and Technology Volume 34, 2013 - Issue 6
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Original Articles

Influence of Emulsifiers on Acrylate Latex Blends

Qing Ye Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, P. R. China
,
Liang-Fang Zhai Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, P. R. China
,
Nian-Nian Fan Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, P. R. China
,
De-Ping Lu Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, P. R. China
&
Rong Guan Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, P. R. ChinaCorrespondence[email protected]
Pages 859-869 | Received 08 Nov 2011, Accepted 30 Nov 2011, Published online: 23 May 2013
 
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Abstract

The poly(methyl methacrylate/butyl acrylate/acrylic acid) [P(MMA/BA/AA)] and poly (styrene/butyl acrylate/acrylic acid) [P(St/BA/AA)] latexes were synthesized using the emulsifier octylphenol polyoxyethylene(10) ether (OP-10) and ammonium sulfate allyloxy nonylphenoxy poly(ethyleneoxy)(10) ether(DNS-86). The optimum amount of OP-10 and DNS-86 was 1.5% and 2.5% respectively. The P(MMA/BA/AA) and P(St/BA/AA) latex containing 1.5% OP-10 or 2.5% DNS-86 were blended pairwise. The performances of latex blends and parent latexes as a function of emulsifiers content in parent latexes were determined. The results indicated that the stability of latex blends is favorable, and particle size distribution was more uniform and thermal stability was improved after blending.

Notes

a P(MMA/BA/AA) latexes named A, P(St/BA/AA) latexes named B.

b Accounted for the percentage of total monomers.

a Accounted for the percentage of latex blend.

a OP-10A/DNS-86A is latex blend of OP-10A and DNS-86A; OP-10A/DNS-86B is latex blend of OP-10A and DNS-86B; OP-10B/DNS-86B is latex blend of OP-10B and DNS-86B; OP-10B/DNS-86A is latex blend of OP-10B and DNS-86A.

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