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Original Articles

Synthesis and properties of highly birefringent liquid crystalline materials: 2,5-bis(5-alkyl-2-butadinylthiophene-yl) styrene monomers

, , , , , , & show all
Pages 69-76 | Received 14 Aug 2009, Accepted 28 Sep 2009, Published online: 12 Jan 2010
 

Abstract

In order to obtain liquid crystals with high birefringence (Δn), a series of new liquid crystals monomers incorporating styrene, a 2,5-disubstituted thiophene ring and diacetylenes, which were highly conjugated along the molecular long axis, were synthesized. Their physical properties were evaluated. As expected, they exhibited high Δn values of 0.4–0.7 and a low melting point and were of potential use for polymer-dispersed liquid crystal displays (PDLCDs), cholesteric displays and laser beam steering applications.

Acknowledgement

This research was supported by the National Natural Science Foundation of China (Grant nos: 20634010, 20874002, 20874003 and 20974002).

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