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Invited Articles

Pentaalkoxytriphenylene monoesters and their dyads; structural factors influencing columnar and nematic mesophase behaviour

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Pages 1174-1183 | Received 13 Jul 2021, Published online: 08 Nov 2021

Figures & data

Figure 1. Examples of discotic liquid crystals, including dyads and twins.

Figure 1. Examples of discotic liquid crystals, including dyads and twins.

Scheme 1. Synthesis, structures and mesophase behaviour of penta(hexyloxy)triphenylene monoesters 8 (Hx = n-hexyl).

Scheme 1. Synthesis, structures and mesophase behaviour of penta(hexyloxy)triphenylene monoesters 8 (Hx = n-hexyl).

Scheme 2. The synthesis of triphenylene ester dyads and an example of the unwanted side products produced during DCC coupling (Hx = n-hexyl).

Scheme 2. The synthesis of triphenylene ester dyads and an example of the unwanted side products produced during DCC coupling (Hx = n-hexyl).

Scheme 3. The synthesis of triphenylene ester triad 16 (Hx = n-hexyl).

Scheme 3. The synthesis of triphenylene ester triad 16 (Hx = n-hexyl).

Figure 2. (Colour online) Structures and mesophase behaviour of triphenylene ester dyads (Hx = n-hexyl).

Figure 2. (Colour online) Structures and mesophase behaviour of triphenylene ester dyads (Hx = n-hexyl).