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Original Articles

Effect of Acoustic Radiation on DMA Resolution

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Pages 866-870 | Received 17 Dec 2005, Accepted 05 Aug 2005, Published online: 23 Feb 2007

Figures & data

FIG. 1 Full width at half height (FWHH) versus peak voltage for the transfer function of the DMA of CitationRosser et al. (2005) when classifying tetraheptyl ammonium ions. Note the resonance arising at about 410 volts, attributed to acoustic radiation.

FIG. 1 Full width at half height (FWHH) versus peak voltage for the transfer function of the DMA of CitationRosser et al. (2005) when classifying tetraheptyl ammonium ions. Note the resonance arising at about 410 volts, attributed to acoustic radiation.

Table 1 Electrical mobility of the three ions used

FIG. 2 Performance of the Río Arriba DMA (RA) with three different ions. Note the dip down to almost ideal behavior near the sonic point (rightmost datum for each ion). (a) FWHH versus voltage (volt); (b) FWHH/Z1/2 versus Re1/2, with Z in cm2/V/s.

FIG. 2 Performance of the Río Arriba DMA (RA) with three different ions. Note the dip down to almost ideal behavior near the sonic point (rightmost datum for each ion). (a) FWHH versus voltage (volt); (b) FWHH/Z1/2 versus Re1/2, with Z in cm2/V/s.

FIG. 3 Mobility spectra for the tetraheptyl ammonium ion in the Herrmann DMA. While pumping power increases monotonically from left to right, the peak positions exhibit a saturation phenomenon indicating that sonic conditions have been reached. Vp is in volts.

FIG. 3 Mobility spectra for the tetraheptyl ammonium ion in the Herrmann DMA. While pumping power increases monotonically from left to right, the peak positions exhibit a saturation phenomenon indicating that sonic conditions have been reached. Vp is in volts.

FIG. 4 FWHH versus peak voltage for the Herrmann DMA, using either methyl4N+ ions (a), or ethyl4N+ (b). Vp is in volts.

FIG. 4 FWHH versus peak voltage for the Herrmann DMA, using either methyl4N+ ions (a), or ethyl4N+ (b). Vp is in volts.

FIG. 5 Resolution of the Herrmann DMA in a representation similar to that of b, separating the flow effects in the horizontal variable. This variable is now the Mach number in the working section, showing with greater clarity the transonic increase in resolution.

FIG. 5 Resolution of the Herrmann DMA in a representation similar to that of Figure 2b, separating the flow effects in the horizontal variable. This variable is now the Mach number in the working section, showing with greater clarity the transonic increase in resolution.

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