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Original Articles

Mechanisms of the Formation of Silica Particles from Precursors with Different Volatilities by Flame Spray Pyrolysis

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Pages 911-920 | Received 04 Feb 2009, Accepted 22 Apr 2009, Published online: 16 Jun 2009

Figures & data

FIG. 1 Schematic drawing of the experimental set-up.

FIG. 1 Schematic drawing of the experimental set-up.

FIG. 2 Temperature profile of the flame.

FIG. 2 Temperature profile of the flame.

FIG. 3 (a) Specific surface areas and average particle sizes of silica particles made from TEOS at various concentrations at 1610°C. TEM micrographs of silica particles for (b) 0.1, (c) 0.3, and (d) 0.5 M. (e) Specific surface areas and average particle sizes of silica particles produced from TEOS at various heights from the top of the burner at 0.3 M and 1610°C.

FIG. 3 (a) Specific surface areas and average particle sizes of silica particles made from TEOS at various concentrations at 1610°C. TEM micrographs of silica particles for (b) 0.1, (c) 0.3, and (d) 0.5 M. (e) Specific surface areas and average particle sizes of silica particles produced from TEOS at various heights from the top of the burner at 0.3 M and 1610°C.

FIG. 4 (a) Specific surface areas and average particle sizes of silica particles made from silicic acid at various concentrations at 1610°C. TEM micrographs of silica particles for (b) 0.1, (c) 0.3, and (d) 0.5 M.

FIG. 4 (a) Specific surface areas and average particle sizes of silica particles made from silicic acid at various concentrations at 1610°C. TEM micrographs of silica particles for (b) 0.1, (c) 0.3, and (d) 0.5 M.

FIG. 5 (a) Specific surface areas and average particle sizes of silica particles made from TEOS at various temperatures and the precursor concentration of 0.5 M. TEM micrographs of silica particles obtained at (b) 1200, (c) 1350, (d) 1610, and (e) 1710°C.

FIG. 5 (a) Specific surface areas and average particle sizes of silica particles made from TEOS at various temperatures and the precursor concentration of 0.5 M. TEM micrographs of silica particles obtained at (b) 1200, (c) 1350, (d) 1610, and (e) 1710°C.

FIG. 6 (a) Specific surface areas and average particle sizes of silica particles made from silicic acid at various temperatures and the precursor concentration of 0.5 M. TEM micrographs of silica particles obtained at (b) 1200, (c) 1350, (d) 1610, and (e) 1710°C.

FIG. 6 (a) Specific surface areas and average particle sizes of silica particles made from silicic acid at various temperatures and the precursor concentration of 0.5 M. TEM micrographs of silica particles obtained at (b) 1200, (c) 1350, (d) 1610, and (e) 1710°C.

FIG. 7 Particle formation mechanisms. (A) vapor phase reaction (VPR), (B) mixture of VPR and intra-droplet reaction (IDR), and (C) IDR.

FIG. 7 Particle formation mechanisms. (A) vapor phase reaction (VPR), (B) mixture of VPR and intra-droplet reaction (IDR), and (C) IDR.

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