1,818
Views
12
CrossRef citations to date
0
Altmetric
Original Articles

Characterization of carbon fractal-like aggregates by size distribution measurements and theoretical calculations

, , , , , , & show all
Pages 133-147 | Received 24 Apr 2015, Accepted 04 Dec 2015, Published online: 25 Jan 2016

Figures & data

Figure 1. Schematic diagram outlining the basic components of the spark discharge source (a) RCL circuit and (b) spark generator.

Figure 1. Schematic diagram outlining the basic components of the spark discharge source (a) RCL circuit and (b) spark generator.

Figure 2. Experimental set up to generate polydisperse aerosol nanoparticles.

Figure 2. Experimental set up to generate polydisperse aerosol nanoparticles.

Figure 3. SEM images of carbon nanoparticles produced by a discharge ionization source.

Figure 3. SEM images of carbon nanoparticles produced by a discharge ionization source.

Figure 4. Comparison of the SMPS-calculated total Fuchs surface area with the CEPI-measured total Fuchs surface area.

Figure 4. Comparison of the SMPS-calculated total Fuchs surface area with the CEPI-measured total Fuchs surface area.

Figure 5. Comparison of theoretical and measured Fuchs surface area per particle. The normalized Fuchs surface area was obtained by dividing the CEPI response by total number concentration obtained from SMPS measurements.

Figure 5. Comparison of theoretical and measured Fuchs surface area per particle. The normalized Fuchs surface area was obtained by dividing the CEPI response by total number concentration obtained from SMPS measurements.

Figure 6. Comparison of the Fuchs surface area measured by the CEPI and the surface area calculated by the number distribution from SMPS assuming a monodisperse aerosol.

Figure 6. Comparison of the Fuchs surface area measured by the CEPI and the surface area calculated by the number distribution from SMPS assuming a monodisperse aerosol.

Figure 7. Experimental and calculated effective density (normalized by the bulk particle density) as a function of the geometric mean mobility diameter (normalized by the primary particle diameter). Symbols are described in the main text.

Figure 7. Experimental and calculated effective density (normalized by the bulk particle density) as a function of the geometric mean mobility diameter (normalized by the primary particle diameter). Symbols are described in the main text.

Figure 8. Calculated number of primary particles as a function of the geometric mean mobility diameter of the SMPS number distributions. The primary-particle diameter was 12.7 nm. Symbols are described in the main text.

Figure 8. Calculated number of primary particles as a function of the geometric mean mobility diameter of the SMPS number distributions. The primary-particle diameter was 12.7 nm. Symbols are described in the main text.

Figure 9. Calculated and measured dynamic shape factor (χ) as a function of the geometric mean mobility diameter of the SMPS number distributions.

Figure 9. Calculated and measured dynamic shape factor (χ) as a function of the geometric mean mobility diameter of the SMPS number distributions.

Figure 10. Comparison between reference mobility diameter (taken to be the GMD of the SMPS number distributions) and calculated mobility diameters.

Figure 10. Comparison between reference mobility diameter (taken to be the GMD of the SMPS number distributions) and calculated mobility diameters.

Figure 11. Percentage difference between reference and theoretically determined mobility diameters as a function of number of primary particles.

Figure 11. Percentage difference between reference and theoretically determined mobility diameters as a function of number of primary particles.
Supplemental material

UAST_1134763_Supplemental_File.zip

Download Zip (185 KB)

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.