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Original Articles

Determination of the Size Distribution of Polydisperse Nanoparticles with Single-Particle Mass Spectrometry: The Role of Ion Kinetic Energy

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Pages 162-169 | Received 01 Apr 2004, Accepted 01 Oct 2004, Published online: 17 Aug 2010

Figures & data

FIG. 1 Schematic of SPMS.

FIG. 1 Schematic of SPMS.

FIG. 2 Relationship between the cube root of the integrated signal intensity and particle size for three materials.

FIG. 2 Relationship between the cube root of the integrated signal intensity and particle size for three materials.

FIG. 3 Typical mass spectrum of a NaCl nanoparticle (∼ 70 nm).

FIG. 3 Typical mass spectrum of a NaCl nanoparticle (∼ 70 nm).

FIG. 4 Histogram of Na fraction in polydisperse NaCl nanoparticles.

FIG. 4 Histogram of Na fraction in polydisperse NaCl nanoparticles.

FIG. 5 Saturation of ion yield with pulse energy.

FIG. 5 Saturation of ion yield with pulse energy.

FIG. 6 (a) Schematic of TOF tube assembly from ion generation to its detection. (b) Geometrical configuration of ion cloud used in simulation. x denotes the direction toward MCP detector along the centerline of time of flight tube, while y direction is the horizontal direction.

FIG. 6 (a) Schematic of TOF tube assembly from ion generation to its detection. (b) Geometrical configuration of ion cloud used in simulation. x denotes the direction toward MCP detector along the centerline of time of flight tube, while y direction is the horizontal direction.

FIG. 7 Simulation algorithm for TOF mass spectrum and detection efficiency.

FIG. 7 Simulation algorithm for TOF mass spectrum and detection efficiency.

FIG. 8 Effect of initial KE on detection efficiency.

FIG. 8 Effect of initial KE on detection efficiency.

FIG. 9 Total ion yield as a function of flight tube steering voltage.

FIG. 9 Total ion yield as a function of flight tube steering voltage.

FIG. 10 Size distribution as measured by SPMS and comparison with SMPS.

FIG. 10 Size distribution as measured by SPMS and comparison with SMPS.

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