Wettability modification of lignite by adsorption of alkyltrimethylammonium bromides with different alkyl chain length

ABSTRACT

To overcome the problem of moisture re-adsorption of dried lignite with common evaporation drying methods, a set of linear alkyl quaternary ammonium surfactants (C₁₀TAB, C₁₂TAB, and C₁₆TAB) were used to modify lignite surface, and the effects of alkyl chain length on the adsorption characteristics of surfactants and wettability of lignite surface were evaluated. Pseudo-first and pseudo-second-order kinetic models and Langmuir model were, respectively, used to simulate adsorption kinetics and adsorption isotherms. The results showed that three surfactants gradually formed double-layer adsorption on lignite surface and the loading of surfactant increased with the length of alkyl chain. X-ray photoelectron spectroscopy analysis showed that C₃H₉N⁺ moiety of the surfactants would preferentially interact with O˭C‒O groups of lignite. Results of wetting heating and moisture re-adsorption showed that three surfactants obviously decreased hydrophilicity and restrained moisture re-adsorption of lignite, but with the formation of double-layer adsorption, hydrophilic headgroups of surfactant faced outward, which caused increase in hydrophilicity of lignite. As a result of two opposite effects of surfactant chain length on lignite wettability, the effect of C₁₂TAB on decreasing hydrophilicity was the best among the three chosen surfactants.

KEYWORDS:

• Adsorption
• alkyl chain length
• lignite
• surfactant
• wettability