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Food & Nutrition Science

Promotion or suppression of glucose isomerization in subcritical aqueous straight- and branched-chain alcohols

, &
Pages 470-474 | Received 28 Aug 2014, Accepted 26 Sep 2014, Published online: 27 Oct 2014

Figures & data

Fig. 1. Changes in the fraction of remaining glucose with residence time in (♢) subcritical water and 60% (v/v) subcritical aqueous alcohols ((□) methanol, (△) ethanol, (○) 1-propanol, (▽) 2-propanol, and (▷) t-butyl alcohol) at 180 °C.

Fig. 1. Changes in the fraction of remaining glucose with residence time in (♢) subcritical water and 60% (v/v) subcritical aqueous alcohols ((□) methanol, (△) ethanol, (○) 1-propanol, (▽) 2-propanol, and (▷) t-butyl alcohol) at 180 °C.

Fig. 2. Yields of fructose and mannose derived from glucose at various residence times in subcritical water and in 60% (v/v) subcritical aqueous alcohols at 180 °C.

Note: Symbols are the same as those in Fig. , and the open and closed symbols represent the yields of fructose and mannose, respectively.

Fig. 2. Yields of fructose and mannose derived from glucose at various residence times in subcritical water and in 60% (v/v) subcritical aqueous alcohols at 180 °C.Note: Symbols are the same as those in Fig. 1, and the open and closed symbols represent the yields of fructose and mannose, respectively.

Fig. 3. Effects of the alcohol concentration on the selectivities of (♢) fructose and (□) mannose, (△) fraction of disappeared hexoses, and (○) yield of fructose for the treatment of glucose at 180 °C for 500 s.

Note: (a) Methanol, (b) 1-propanol, (c) 2-propanol.

Fig. 3. Effects of the alcohol concentration on the selectivities of (♢) fructose and (□) mannose, (△) fraction of disappeared hexoses, and (○) yield of fructose for the treatment of glucose at 180 °C for 500 s.Note: (a) Methanol, (b) 1-propanol, (c) 2-propanol.

Fig. 4. Changes in the fraction of remaining glucose with residence time at 180 °C in (♢) 80%, (□) 60%, (△) 40%, (○) 20%, and (▷) 0% (v/v) t-butyl alcohol and at (■) 200 °C in 60% (v/v) t-butyl alcohol.

Fig. 4. Changes in the fraction of remaining glucose with residence time at 180 °C in (♢) 80%, (□) 60%, (△) 40%, (○) 20%, and (▷) 0% (v/v) t-butyl alcohol and at (■) 200 °C in 60% (v/v) t-butyl alcohol.

Fig. 5. Yields of fructose derived from glucose at different residence times in subcritical aqueous t-butyl alcohol.

Note: The symbols are the same as those in Fig. .

Fig. 5. Yields of fructose derived from glucose at different residence times in subcritical aqueous t-butyl alcohol.Note: The symbols are the same as those in Fig. 4.

Fig. 6. Effects of t-butyl alcohol concentrations on (♢) the selectivity of fructose, (△) the fraction of degraded hexoses, and (○) the yield of fructose for the treatment of glucose at 180 °C for 1000 s.

Fig. 6. Effects of t-butyl alcohol concentrations on (♢) the selectivity of fructose, (△) the fraction of degraded hexoses, and (○) the yield of fructose for the treatment of glucose at 180 °C for 1000 s.

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