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Food & Nutrition Science (Note)

Cucumis sativus secretes 4′-ketoriboflavin under iron-deficient conditions

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Pages 363-367 | Received 23 Jul 2015, Accepted 25 Aug 2015, Published online: 02 Nov 2015

Figures & data

Fig. 1. Flavin compounds present in (A) standard solution [FAD, FMN, and riboflavin (Rbfl)], and in C. sativus nutrient solution cultivated under (B) iron-deficient and (C) iron-sufficient conditions.

Fig. 1. Flavin compounds present in (A) standard solution [FAD, FMN, and riboflavin (Rbfl)], and in C. sativus nutrient solution cultivated under (B) iron-deficient and (C) iron-sufficient conditions.

Fig. 2. MS/MS spectrum of riboflavin (A) and an unidentified flavin compound (B) in the positive ionization mode.

Fig. 2. MS/MS spectrum of riboflavin (A) and an unidentified flavin compound (B) in the positive ionization mode.

Fig. 3. Structure of riboflavin (A) and 4′-ketoriboflavin (B) as determined using 1H NMR (C), 13C NMR (D), NOESY (E), and HMBC (F).

Fig. 3. Structure of riboflavin (A) and 4′-ketoriboflavin (B) as determined using 1H NMR (C), 13C NMR (D), NOESY (E), and HMBC (F).

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