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International Journal of Polymer Analysis and Characterization Volume 25, 2020 - Issue 1
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Original Articles

Novel interpenetrating polymer network composed of poly(butyl acrylates) and poly(ethyl-hexyl acrylate)

Kamel Eddine BoudraaBiology Department, Faculty of Sciences, University of Saida, Saida, Algeria; ;Laboratoire de Recherche sur les Macromolécules, Département de Physique, Faculté des Sciences, Université Abou Bakr Belkaïd, Tlemcen, Algeria; Correspondence[email protected]
ORCID Iconhttp://orcid.org/0000-0001-8045-0586View further author information
ORCID Icon,
Tewfik BouchaourLaboratoire de Recherche sur les Macromolécules, Département de Physique, Faculté des Sciences, Université Abou Bakr Belkaïd, Tlemcen, Algeria; View further author information
,
Christophe BeyensUnité de Matériaux et de Transformations UMET (UMR CNRS N°8207), Université des Sciences et Technologies de Lille, Villeneuve d’Ascq Cedex, FranceView further author information
&
Ulrich MaschkeUnité de Matériaux et de Transformations UMET (UMR CNRS N°8207), Université des Sciences et Technologies de Lille, Villeneuve d’Ascq Cedex, FranceView further author information
Pages 18-33 | Received 13 May 2019, Accepted 24 Feb 2020, Published online: 17 Mar 2020
 
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Abstract

Novel full acrylic interpenetrating polymer networks (IPNs) made up of the Poly Ethyl- Hexyl Acrylate (PEHA) and Poly Butyl-Acrylate (PABu) networks with various crosslinking ratios were characterized by means of Infrared spectroscopy, swelling, DSC and TGA techniques. The systems are prepared via photo-polymerization by UV-curing of monomers in the presence of a difunctional crosslinker and a photo-initiator. The physical properties of the IPNs are mainly influenced by the quantity of the monomer present in the IPNs and increasing the crosslinker prevents formation of unreacted oligomers inside the IPNs. Surprisingly, the IPNs with 0.5% crosslinker does not present any phase separation.

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Funding

This work was supported by University Dr Tahar Moulay-Saida- (Algeria).

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