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Journal of Asian Natural Products Research Volume 11, 2009 - Issue 1
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Original Articles

A new sesquiterpenoid metabolite from Psilocybe samuiensis

Surachai Pornpakakul Research Centre for Bioorganic Chemistry, Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok, ThailandCorrespondence[email protected]
,
Sunisa Suwancharoen Research Centre for Bioorganic Chemistry, Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok, Thailand
,
Amorn Petsom Research Centre for Bioorganic Chemistry, Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok, Thailand
,
Sophon Roengsumran Research Centre for Bioorganic Chemistry, Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok, Thailand
,
Nongnuj Muangsin Research Centre for Bioorganic Chemistry, Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok, Thailand
,
Narongsak Chaichit Department of Physics, Faculty of Science and Technology, Thammasat University, Pathumthani, Thailand
,
Jittra Piapukiew Department of Botany, Faculty of Science, Chulalongkorn University, Bangkok, Thailand
,
Prakistin Sihanonth Department of Microbiology, Faculty of Science, Chulalongkorn University, Bangkok, Thailand
&
John W. Allen P.O. Box 45164 Seattle, Washington, DC, USA
 show all
Pages 12-17 | Received 29 Feb 2008, Accepted 24 Jul 2008, Published online: 28 Jan 2009
 
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Abstract

A novel 2,3-secoaromadendrane-type sesquiterpenoid metabolite, psilosamuiensin A (1), was isolated from the broth of Psilocybe samuiensis. The structure of psilosamuiensin A was established by spectroscopic data and its configurations were confirmed by single crystal X-ray crystallographic analysis. This is the first report of psilosamuiensin A found in the genus Psilocybes.

Acknowledgements

We thank Higher Education Commission Grants for Graduate Dissertation for financial support. Department of Chemistry, Faculty of Science, Chulalongkorn University, the Rachadapiseksompoj Endowment, Chulalongkorn University, National Center of Excellence for Petroleum, Petrochemicals and Advanced Materials (NCE-PPAM) and the Thailand Research Fund (RTA4880008) are also gratefully acknowledged.

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