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Fullerenes, Nanotubes and Carbon Nanostructures Volume 14, 2006 - Issue 2-3
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Original Articles

Equilibrium Phase Diagram of Polymerized C60 and Kinetics of Decomposition of the Polymerized Phases

M. V. Korobov Department of Chemistry, Moscow State University, Moscow, RussiaCorrespondence[email protected]
,
A. G. Bogachev Department of Chemistry, Moscow State University, Moscow, Russia
,
V. M. Senyavin Department of Chemistry, Moscow State University, Moscow, Russia
,
A. A. Popov Department of Chemistry, Moscow State University, Moscow, Russia
,
V. A. Davydov Institute of High‐Pressure Physics of RAS, Moscow District, Russia
,
A. V. Rakhmanina Institute of High‐Pressure Physics of RAS, Moscow District, Russia
&
A. V. Markin Chemistry Institute, Nizhny Novgorod State University, Nizhny Novgorod, Russia
 show all
Pages 401-407 | Published online: 22 Aug 2006
 
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Abstract

Equilibrium phase diagram (T=0–1000 K; p=0–8 GPa) of pressure‐temperature polymerized C60 has been constructed. It included rhombohedral; orthorhombic and tetragonal polymerized phases of C60 along with fcc monomeric phases of C60. The isothermal kinetics of depolymerization (T=373–513 K) of the O‐, R‐, T‐ and D‐phases was studied by means of the IR‐spectroscopy. The isothermal rate of decomposition goes up along the series: (T‐)<(O‐)<(R‐)<(D‐).

Acknowledgment

This study was supported by the RFBR grant 03‐03‐32179.

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