The Generalized Approach to Electrolytic Systems: I. Physicochemical and Analytical Implications

Abstract

The generalized electron balance (GEB) concept is derived from elementary rules of the matter preservation and applied for resolution of complex electrolytic systems, with special emphasis put on redox systems. Interrelations between different fundamental rules of the matter preservation, referred to electrolytic systems, are indicated. Equilibrium and metastable systems are considered. Advantages of the generalized approach to electrolytic systems (GATES) are evidenced.

Keywords:

• equilibrium analysis
• titration
• computer simulation