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Original Articles

Titanocene(II)-Promoted Reactions of 2-(Alk-1-yn-1-yl)-2-(Trialkylsilyl)-1,3-dithianes with Olefins and Carbonyls

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Pages 1291-1296 | Received 09 Jul 2004, Accepted 05 Oct 2004, Published online: 16 Aug 2006
 

Abstract

Trialkylsilyl group-directed regioselective transformations of alkynyl thioacetals to alkynylcyclopropanes and enynes are described.

Acknowledgments

This research was supported by a Grant-in-Aid for Scientific Research (No. 14340228) and Grant-in-Aid for Scientific Research on Priority Areas (A) “Exploitation of Multi-Element Cyclic Molecules” (No. 14044022) from the Ministry of Education, Culture, Sports, Science and Technology, Japan. This work was carried out under the 21st Century COE program of “Future Nano-materials” in Tokyo University of Agriculture & Technology.

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