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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 183, 2008 - Issue 2-3
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Original Articles

Novel Heterocyclic P-Ligands: Synthesis and Application in Pt(II) Complexes

György Keglevich Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
Andrea Kerényi Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
Melinda Sipos Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
,
Annamária Balassa Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary
&
Tamás Körtvélyesi Department of Physical Chemistry, University of Szeged, Szeged, Hungary
Pages 440-444 | Published online: 20 Jun 2008
 
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Abstract

3-Diphenylphosphino-1,2,3,6-tetrahydro- and 1,2,3,4,5,6-hexahydro-phosphinines, as well as dibenzo[c,e][1,2]oxaphosphorines (L) were prepared and used in the synthesis of the corresponding cis chelate Pt(II) complexes and PtCl2L2 complexes, respectively. The latter family of compounds includes 7-membered ring Pt(II) complexes.

Acknowledgments

This project was supported by the European Union and the Hungarian State (GVOP- 3.2.2.-2004-07-0006/3.0) and jointly by the Hungarian Scientific Research Fund (OTKA, Grant No. T067679).

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