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Original Articles

Poly(Ethylene) Glycol as a Green and Reusable Solvent in the Oxidation of Sulfides to Sulfoxides Using NaClO

Pages 1381-1385 | Received 17 Mar 2009, Accepted 20 May 2009, Published online: 02 Jul 2010
 

Abstract

This article describes selective oxidation of a range of sulfides to the corresponding sulfoxides in good yields by NaClO in poly(ethylene) glycol as a green and reusable solvent using sulfuric acid as an efficient acid catalyst. The new method compares favorably with previous methods in literature. A separable mixture of two new diastereoisomers is reported.

Acknowledgments

We thank Semnan University for supporting this work.

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