1,947
Views
55
CrossRef citations to date
0
Altmetric
Technical Papers

Absorption of NO and NO2 in Caprolactam Tetrabutyl Ammonium Halide Ionic Liquids

, , , , &
Pages 1393-1397 | Published online: 23 Nov 2011

Figures & data

Figure 1. The mole fraction solubility (x) of NO as a function of temperature in different (2:1 mole ratio) ILs.

Figure 1. The mole fraction solubility (x) of NO as a function of temperature in different (2:1 mole ratio) ILs.

Figure 2. The mole fraction solubility (x) of NO2 as a function of temperature in different (2:1 mole ratio) ILs.

Figure 2. The mole fraction solubility (x) of NO2 as a function of temperature in different (2:1 mole ratio) ILs.

Figure 3. The color change of caprolactam tetrabutyl ammonium bromide ionic liquids with different concentrations of NOx. (a) Caprolactam tetrabutyl ammonium bromide ionic liquid; (b) after bubbling NO for 20 min; (c) after bubbling NO2 for 20 min.

Figure 3. The color change of caprolactam tetrabutyl ammonium bromide ionic liquids with different concentrations of NOx. (a) Caprolactam tetrabutyl ammonium bromide ionic liquid; (b) after bubbling NO for 20 min; (c) after bubbling NO2 for 20 min.

Figure 4. The mole fraction solubility (x) of NO as a function of temperature at different mole ratios of CPL and TBAB.

Figure 4. The mole fraction solubility (x) of NO as a function of temperature at different mole ratios of CPL and TBAB.

Figure 5. The mole fraction solubility (x) of NO2 as a function of temperature at different mole ratios of CPL and TBAB.

Figure 5. The mole fraction solubility (x) of NO2 as a function of temperature at different mole ratios of CPL and TBAB.

Figure 6. The mole fraction solubility (x) of N2, CO2, NO, and NO2 as a function of temperature at CPL and TBAB (mole ratio, 2:1).

Figure 6. The mole fraction solubility (x) of N2, CO2, NO, and NO2 as a function of temperature at CPL and TBAB (mole ratio, 2:1).

Figure 7. The mole fraction solubility (x) of NOx desorption by vacuum rotary evaporator at different mole ratios of CPL and TBAB. After the ILs were reused, the absorption of gas was equal to the amount of absorbed gas. ▪ 2:1; • 3:1 (the desorption of NO); ▴ 2:1; ▾ 3:1 (the desorption of NO2).

Figure 7. The mole fraction solubility (x) of NOx desorption by vacuum rotary evaporator at different mole ratios of CPL and TBAB. After the ILs were reused, the absorption of gas was equal to the amount of absorbed gas. ▪ 2:1; • 3:1 (the desorption of NO); ▴ 2:1; ▾ 3:1 (the desorption of NO2).

Figure 8. 1H-NMR spectra ((CD3)2SO, 500 Hz) of CPL-TBAB IL and CPL-TBAB IL with NOx gas.

Figure 8. 1H-NMR spectra ((CD3)2SO, 500 Hz) of CPL-TBAB IL and CPL-TBAB IL with NOx gas.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.