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Journal of Macromolecular Science, Part A
Pure and Applied Chemistry
Volume 43, 2006 - Issue 6
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Original Articles

Bulk Copolymerization of Styrene and Methyl Methacrylate at Elevated Temperatures

S. Shankar Institute for Polymer Research, Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada
,
R. Khesareh Institute for Polymer Research, Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada
,
Dr. N. McManus Institute for Polymer Research, Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, CanadaCorrespondence[email protected]
&
A. Penlidis Institute for Polymer Research, Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada
Pages 871-878 | Received 01 Feb 2006, Accepted 01 Feb 2006, Published online: 07 Feb 2007
 
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Abstract

Reactivity ratios and full conversion range data (conversion, copolymer composition, molecular weight averages, glass transition temperature) are presented for styrene (STY)/methyl methacrylate (MMA)/copolymerization at elevated temperatures (130 and 150°C), a region where polymerization studies are scarce for the system, both for purely thermal polymerization and for peroxide‐initiated ones.

Acknowledgements

We gratefully thank for funding: the Natural Sciences and Engineering Research Council (NSERC) of Canada, and the Canada Research Chair (CRC) program.

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