Viscosity-Temperature Behavior of Hydroxypropyl Cellulose Solution in Presence of an Electrolyte or a Surfactant: A Convenient Method to Determine the Cloud Point of Polymer Solutions

Abstract

The viscosity of hydroxypropyl cellulose (HPC) solution with or without an additive has been measured continuously as a function of temperature with the help of a vibro-viscometer. The viscosity of the polymer solution showed a gradual decrease initially with increase in temperature until a particular point beyond which there was a sharp decrease in the viscosity, which coincided with the clouding of the solution. The cloud point temperature (CP) of the polymer solution was determined from the first derivative plot of viscosity vs. temperature. Effect of addition of an electrolyte or a surfactant on the CP of HPC solution has also been studied. While a decrease in CP of HPC solution in presence of fluoride, chloride, or bromide ions was observed, presence of iodide or thiocyanide ions led to an increase in the CP. However, presence of an ionic surfactant initially lowered the CP but beyond a particular surfactant concentration a sharp increase in cloud point was observed due to interaction of the surfactant with the polymer. The results suggest that surfactants with longer hydrophobic tail or more hydrophobic groups have more affinity for HPC.

Keywords:

• Cloud point
• viscosity
• additives
• surfactants
• hydrophobic interactions

Additional information

Funding

The financial support from the Department of Science and Technology, New Delhi in the form of Research Project No. SR/S1/PC-34/2007 dated 15/12/2008 and University Grants Commission, New Delhi, No. F.37-511/2009(SR) are gratefully acknowledged.