Synthesis of hydroxy sodalite from coal fly ash using waste industrial brine solution

Abstract

The effect of using industrial waste brine solution instead of ultra pure water was investigated during the synthesis of zeolites using three South African coal fly ashes as Si feedstock. The high halide brine was obtained from the retentate effluent of a reverse osmosis mine water treatment plant. Synthesis conditions applied were; ageing of fly ash was at 47°C for 48 hours, and while the hydrothermal treatment temperature was set at 140°C for 48 hours. The use of brine as a solvent resulted in the formation of hydroxy sodalite zeolite although unconverted mullite and hematite from the fly ash feedstock was also found in the synthesis product.

Keywords:

• Hydroxy sodalite
• coal fly ash
• ageing process
• hydrothermal synthesis
• brine solution

Acknowledgments

The authors would like to acknowledge Water Research Commission (WRC), National Research Foundation (NRF) and Coaltech 2020 for providing the funds to make this study possible.