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Technical Papers

Novel insights into enhanced dewatering of waste activated sludge based on the durable and efficacious radical generating

&
Pages 1151-1163 | Received 12 Feb 2016, Accepted 09 May 2016, Published online: 18 May 2016

Figures & data

Figure 1. Performance of Fe(II)-activated CaO2 for enhanced dewatering of WAS. Left: CST; right: SRF. (a, b) Effect of CaO2 dosage on the dewaterability of WAS. (c, d) Effect of Fe(II) dosage on the dewaterability of WAS. (e, f) Effect of initial pH on the dewaterability of WAS.

Figure 1. Performance of Fe(II)-activated CaO2 for enhanced dewatering of WAS. Left: CST; right: SRF. (a, b) Effect of CaO2 dosage on the dewaterability of WAS. (c, d) Effect of Fe(II) dosage on the dewaterability of WAS. (e, f) Effect of initial pH on the dewaterability of WAS.

Figure 2. CST of WAS pretreated by conventional Fenton reagent and Fe(II)-activated CaO2.

Figure 2. CST of WAS pretreated by conventional Fenton reagent and Fe(II)-activated CaO2.

Figure 3. Effect of 2-propanol and TCM on the dewatering performance of Fe(II)-activated CaO2.

Figure 3. Effect of 2-propanol and TCM on the dewatering performance of Fe(II)-activated CaO2.

Figure 4. EPR spectra of radicals with DMPO spin trap in pretreated WAS: (a) conventional Fenton reagent; (b) Fe(II)-activated CaO2.

Figure 4. EPR spectra of radicals with DMPO spin trap in pretreated WAS: (a) conventional Fenton reagent; (b) Fe(II)-activated CaO2.

Figure 5. SEM spectra of WAS: (a) raw sludge; (b) pretreated sludge (working voltage: 10 kV; magnification: 25000×).

Figure 5. SEM spectra of WAS: (a) raw sludge; (b) pretreated sludge (working voltage: 10 kV; magnification: 25000×).

Figure 6. Molecular weight distribution of different EPS fractions: (a) S-EPS; (b) LB-EPS; (c) TB-EPS. (The conditioning concentrations were 0.05 g/g DS CaO2 and 0.625 mmol/g DS Fe(II) at an initial pH of 2.)

Figure 6. Molecular weight distribution of different EPS fractions: (a) S-EPS; (b) LB-EPS; (c) TB-EPS. (The conditioning concentrations were 0.05 g/g DS CaO2 and 0.625 mmol/g DS Fe(II) at an initial pH of 2.)

Figure 7. Composition variation of different EPS fractions: (a) protein; (b) polysaccharide.

Figure 7. Composition variation of different EPS fractions: (a) protein; (b) polysaccharide.

Figure 8. EEM spectra of different EPS fractions: (a) S-EPS of raw WAS; (b) S-EPS of pretreated WAS; (c) LB-EPS of raw WAS; (d) LB-EPS of pretreated WAS; (e) TB-EPS of raw WAS; (f) TB-EPS of pretreated WAS.

Figure 8. EEM spectra of different EPS fractions: (a) S-EPS of raw WAS; (b) S-EPS of pretreated WAS; (c) LB-EPS of raw WAS; (d) LB-EPS of pretreated WAS; (e) TB-EPS of raw WAS; (f) TB-EPS of pretreated WAS.

Table 1. Zeta potentials (mV) of different EPS fractions.

Figure 9. Distribution of calcium and iron in pretreated WAS.

Figure 9. Distribution of calcium and iron in pretreated WAS.

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