Role of Ag addition in L1₀ ordering of FePt-based nanocomposite magnets

Abstract

The FePt system has important perspectives as high-temperature corrosion-resistant magnets. In the form of rapidly solidified melt-spun ribbons, FePt-based magnets may exhibit in certain cases a two-phase hard–soft magnetic behaviour. The present paper deals with a microstructural and magnetic study of FePtAgB alloys with increasing Ag content. The aim is to identify and confirm the effect of Ag addition in decreasing the temperature of the FePt disorder–order structural phase transformation. A detailed high-resolution transmission electron microscopy study is employed, and the alternative disposal of hard and soft regions within the two-phase microstructure is observed and interpreted with respect to the X-ray diffraction results. In the as-cast Ag-containing samples, it is shown that there is an optimum of the Ag content for which best magnetic properties are obtained. Ag addition creates a nonlinear behaviour of the coercive field and the ordering parameter, similar to the RKKY interaction-induced interlayer exchange coupling (IEC) observed in magnetic layers separated by non-magnetic spacer layers. Direct formation of the L1₀ phase from the as-cast state in the FePtAgB alloys is reported with magnetic parameters compatible to other exchange spring permanent nanomagnets. These findings open novel perspectives into utilization of such alloys in applications requiring magnets operating in high-temperature industrial environments.

Keywords:

• magnetically ordered materials
• rapid solidification
• magnetic measurements
• transmission electron microscopy
• X-ray diffraction
• nanocomposite magnets

Acknowledgements

This work was supported by the Swiss Enlargement Contribution in the framework of the Romanian-Swiss Research Programme, project IZERZO_142256, Contract No. 6 RO-CH/RSRP/02.10.2012. Financial support from Romanian Ministry of Research, PN II IDEI Project No. 291/2011 is also gratefully acknowledged.