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Molecular Crystals and Liquid Crystals Volume 445, 2006 - Issue 1
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Original Articles

Optical Properties of Poly(Propylene Carbonate) which Contains C60(OH)n Structure in the End of Polymer Chain

Shunichi Aikawa Department of Applied Chemistry, Graduate School of Engineering and Bio-Nano Electronics Research Center, Toyo University, Saitama, Japan
,
Yasuhiko Yoshida Department of Applied Chemistry, Graduate School of Engineering and Bio-Nano Electronics Research Center, Toyo University, Saitama, JapanCorrespondence[email protected]
,
Satoko Nishiyama Bio-Nano Electronics Research Center, Toyo University, Saitama, Japan
,
Hiromichi Noguchi Bio-Nano Electronics Research Center, Toyo University, Saitama, Japan
&
Atsumu Shoji Department of Applied Chemistry, Graduate School of Engineering, Saitama, Japan
Pages 315/[605]-321/[611] | Published online: 23 Aug 2006
 
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ABSTRACT

Poly(propylene carbonate) which contains C60(OH)n structure in the end of polymer chain was synthesized by copolymerization of propylene oxide and CO2 with Et2Zn-C60(OH)n catalytic system. Emission and absorption spectra of the product polymer were determined and discussed. An emission band with a few peaks in UV-region were seen in the emission spectrum.

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