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Abstract
A novel homologous series of 12 symmetrical dimers, viz. 1,1’-Bis[4-(4’-n-alkoxy benzoyloxy)-3-methyl phenyl] cyclohexanes is reported. Nematogenic mesophase commences from the heptyloxy homologue dimer and continues up to the hexadecyloxy dimer in an enantiotropic manner without the exhibition of any smectogenic behavior. The rest of the dimers from methoxy to hexyloxy are nonmesogenic. The textures of the nematic phase are threaded or Schlieren. The transition temperatures and textures of the nematic phase were determined by an optical polarizing microscope equipped with a heating stage. Curves (solid-isotropic/nematic and N-I) of a phase diagram showing mesomorphism behave in normal manner except for a minor deviation at the dodecyloxy derivative. The analytical and spectral data confirm the molecular structure of dimers. The nematogenic mesophase lengths vary between 3.3°C and 26.6°C. The average thermal stability for nematic is 108.26°C; series is partly nematogenic with middle ordered melting type and low degree of mesomorphism. Liquid crystal properties of novel dimer series are compared with the structurally similar other known series.
Acknowledgments
The Authors acknowledge thanks to the Department of Chemistry (DST-FIST Funded & UGC-SAP Sponsored), Saurashtra University, Rajkot, for research work. Authors are also especially thankful to Dr. A.V. Doshi, Ex. Principal M.V.M. Science and Home Science College, Rajkot, for his valuable co-operation during present investigation as and when needed. Also thanks are due to the National Facility for Drug Discovery through New Chemical Entities (NCEs), for analysis of samples.