Energy conversion from electrolyte concentration gradient using charged nano-pores

ABSTRACT

Power generation based on the reversed electro-dialysis (RED) cell is studied both numerically and experimentally in this work. The membrane that separates the concentrated and dilute electrolytes is treated as a charged nano-pore array. Both numerical and experimental results show that the RED cell performance is similar to the typical electrochemical cell having a linearly varied current–voltage relation. The open circuit voltage and short-circuit current depend on the ion selectivity of the nano-pore membrane, which is related to the concentration ratio, pore surface charge density, and pore size. The highest energy conversion efficiencies are approximately 48% and 24% from numerical predictions and experimental measurements, respectively. The reason for this discrepancy is attributed to the inhomogenous pore size and surface charge density distributions of the Al₂O₃ membrane used in these experiments.

KEYWORDS:

• Energy conversion efficiency
• charged nano-pore
• current–voltage relation
• ion selectivity
• reversed electro-dialysis (RED)