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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 38, 2008 - Issue 4
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Original Articles

Jones Reagent Supported on Aluminum Silicate: A New Reagent for Oxidation of Alcohols

Ji‐Dong Lou College of Life Sciences, China Institute of Metrology, Hangzhou, Zhejiang, ChinaCorrespondence[email protected]
,
Li Li Instituto de Tecnologia Química e Biolo´gica, Universidade Nova de Lisboa, Av. da Repu´blica, Oeiras, Portugal
,
Negin Vatanian General Research Laboratory, 401 Professional Drive, Gaithersburg, MD, USA
,
Xiu Lian Lu College of Life Sciences, China Institute of Metrology, Hangzhou, Zhejiang, China
&
Xiaoping Yu College of Life Sciences, China Institute of Metrology, Hangzhou, Zhejiang, China
Pages 370-372 | Received 23 May 2007, Accepted 27 Nov 2007, Published online: 12 Jun 2008
 
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An efficient and selective oxidation of benzyl and secondary alcohols to the corresponding benzaldehydes and ketones, respectively, using Jones reagent supported on aluminum silicate at room temperature under heterogeneous is described, which procedure is an extension of application for Jones reagent. The present oxidations are completed within 10 minutes with the yield between 82–98%, except for 1‐hexanal.

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