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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 43, 2013 - Issue 9
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Original Articles

Synthesis and Structure of a HgCl2 Coordination Polymer With 1,4-Bis(benzimidazole-1-yl-methylene)benzene (bbmb)

Yuqing Chen College of Chemical and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China
,
Chunguang Chen College of Chemical and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China
,
Hong Chen College of Chemical and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China
,
Ting Cao College of Chemical and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China
,
Zhongcheng Yue College of Chemical and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China
,
Xiucun Liu College of Chemical and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China
&
Yunyin Niu College of Chemical and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China; State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, P. R. China
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Pages 1307-1310 | Received 30 Nov 2012, Accepted 09 Dec 2012, Published online: 09 Jul 2013
 
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Abstract

In this study, solution reaction of mercury dichloride with organic multifunctional ligand 1,4-bis(benzimidazole-1-yl-methylene)benzene generated a 1D polymer [HgCl2 (bbmb)·2H2O ·CH3OH]n 1, and the crystal structure has been determined (C46H60Cl4Hg2N8O10), Mr = 1428.00, a = 14.703(15) Å, b = 17.248(17) Å, c = 14.91(2) Å, β = 114.869(10)°, space group C2/c, Z = 2, and V = 3430(7) Å3. In 1 the tetrahedral coordination of Hg(II) and the conformation of the bbmb ligand make it a wave-shaped structure.

Supplemental materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file.

Acknowledgments

The authors acknowledge the NSFC (No.21171148, J1103309, 121045919).

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