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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 44, 2014 - Issue 5
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Original Articles

Synthesis and Characterization of Two New Polymolybdate Clusters Containing Chlorine Based on Mo-POMs and N-heterocycle Templates

Zhong-Cheng Yue College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China
,
Hai-Juan Du College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China
,
Li Li College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China
,
Yu-Jie Ma College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China
,
Kai-Li Ma College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China
&
Yun-Yin Niu College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China; State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, P. R. China
Pages 678-686 | Received 11 Feb 2013, Accepted 05 Mar 2013, Published online: 16 Dec 2013
 
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Abstract

Two new organic-inorganic hybrid materials based on Mo-polyoxometalates and N-heterocycle templates, namely [Ag3 (DIE)6][Mo12O36·ClO4]2 ·Cl (1), and [(IM)4NH4] [Mo12O36·ClO4] (2) [DIE = 1,2-diimidazoloethane, IM = imidazole] have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction. Compounds 1 and 2 possess the classical keggin-type heteropolyoxoanion with Cl as the center atom, and this is the first case. IR spectroscopy and gravimetric analysis were performed to further characterize these compounds.

Acknowledgments

The authors acknowledge the NSFC (No.21171148) and open project of State Key Laboratory of Coordination Chemistry.

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