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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 44, 2014 - Issue 6
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Original Articles

Solvent-Induced Bond Rearrangement in Two Zn(II) Coordination Polymers and The Single-Crystal- to-Single- Crystal Transformation

Jie Du College of Chemistry and Materials Engineering, Guiyang University, Guiyang, P. R. China
,
Guanglong Zou School of Chemistry and Environmental Science, Guizhou Minzu Univeristy, Guiyang, P. R. China
,
Xuelin Wang School of Science, Guizhou Minzu University, Guiyang, P. R. China
&
Bing Xie School of Chemistry and Environmental Science, Guizhou Minzu Univeristy, Guiyang, P. R. China
Pages 793-797 | Received 28 Feb 2013, Accepted 23 Mar 2013, Published online: 25 Feb 2014
 
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Abstract

Two new zinc coordination polymers are synthesized at the present of the different solvent. Complex [Zn(pbc)2]n (1) and complex [Zn(pbc)· (DMF)]n (2) (Hpbc = 3-pyrid-3-ylbenzoic acid, DMF = N,N-dimethyl formamide and NMF = N-methyl formamide) are isomers with one-dimensional frameworks, but the resulting Zn(II) coordination numbers are different. The single-crystal-to-single-crystal transformation appears between complexes 1 and 2.

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