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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 45, 2015 - Issue 6
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Original Articles

Synthesis and Comparative Studies of Cyclopalladated Complexes With Ortho C‒H Activation of Aromatic Rings Bearing Electron Donating and Electron Withdrawing Groups

A. M. NassarChemistry Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, EgyptCorrespondence[email protected]
,
A. M. HassanChemistry Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt
,
N. M. IbraheemOrganometallic Chemistry Department, National Research Center, Dokki, Giza, Egypt
&
B. H. HekalChemistry Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt
Pages 813-820 | Received 27 May 2013, Accepted 02 Nov 2013, Published online: 20 Nov 2014
 
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Abstract

The present study was undertaken to throw more light on the cyclopalladation mechanism. The reactivity of Schiff base ligands {N - (4­methoxy benzylidene) ­4-methoxyaniline (1) and N - (4­nitro benzylidene) ­4­methoxyaniline (2)} by interaction with palladium (II) acetate is allowed to the isolation of different complexes (1a–f) and (2a–f). All the newly synthesized compounds are characterized using elemental analysis, IR, UV-VIS, 1HNMR and mass spectral tools as well as TGA.

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