Abstract
A new coordination polymer, {[Co(Phen)(HCOO)(H2O)Cl]·H2O]}n (1) (Phen = 1, 10-Phenanthroline), has been prepared by hydrothermal method and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 is orthorhombic, space group Pna21 with a = 19.0607(3) Å, b = 11.0557(2) Å, c = 6.5475(1) Å, V = 1379.75(4) Å3, Z = 4, Mr = 355.63, Dc = 1.712 g/cm3, F(000) = 724 and μ = 1.454 mm−1. X-ray diffraction analysis reveals that the title complex 1 displays a one-dimensional chain structure. Furthermore, the thermal stability and fluorescent properties of complex 1 were investigated.
Supplementary Material
Crystallographic data for the structural analysis have been deposited with the Cambridge Crystallographic Data Center, CCDC reference number: 953459. This data can be obtained free of charge at: http://www.ccdc.cam.ac. UK or Cambridge Crystallographic Data Center, 12 Union Road, Cambridge CB2 1EZ, UK (fax: +44-1223-336-33; e-mail: [email protected]).
Funding
This work was financially supported by the National Nature Science Foundation of China (No. 21161006), Program for 155 Excellent Talents in Guangxi Higher Education Institutions (Gui Jiao Ren [2012] 41) and the project of outstanding young teachers' training in higher education institutions of Guangxi.