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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 46, 2016 - Issue 7
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Original Articles

Synthesis, Structure, DNA Binding, and Cleavage of a Zn(II) Complex Constructed by 4,4'-Bipyridine and Phenylacetic Acid

Fuchen ZhaoThe Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, P. R. China
,
Xiaoyu MaThe Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, P. R. China
,
Yang MengThe Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, P. R. China
,
Jing GeThe Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, P. R. China
,
Haitao JinThe Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, P. R. China
,
Sijia LiuThe Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, P. R. China
,
Lin ZhanThe Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, P. R. China
,
Mingchang ZhuThe Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, P. R. China
&
Enjun GaoThe Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, P. R. ChinaCorrespondence[email protected]
 show all
Pages 1041-1046 | Received 28 May 2014, Accepted 31 Dec 2014, Published online: 17 Feb 2016
 
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Abstract

The structure of {Zn1(L1)2(L2)2·4H2O}n (a = 19.8462 (12) Å, b = 8.8249(5) Å, c = 15.7574(10) Å, α = 90º, β = 104.1700(10)º, γ = 90º, V = 2675.8(3) Å3, Z = 4, and space group C2/c) is synthesized and characterized by IR, elemental analysis, and X-ray crystallography. Fluorescence analysis indicates that the complex can bind to CT-DNA. Gel electrophoresis assay demonstrates that the complex can interact with plasmid DNA by intercalation.

Funding

The authors gratefully acknowledge the Natural Science Foundation of China (No. 21171118), the Distinguished Professor Project of Liaoning province and the science and technology special fund of Shenyang City (No. F12-151-9-00).

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