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Articles

Fluorescent-tagged acrylic acid-allylpolyethoxy carboxylate copolymer as a green inhibitor for calcium phosphate in industrial cooling systems

, , , , , , , , & show all
Pages 89-98 | Published online: 24 Aug 2012

Figures & data

Scheme 1 Synthesis of APEL.

Scheme 1 Synthesis of APEL.

Scheme 2 Synthesis of PA.

Scheme 2 Synthesis of PA.

Scheme 3 Synthesis of AA–APEL–PA.

Scheme 3 Synthesis of AA–APEL–PA.

Figure 1 The FT-IR spectra of PA.

Figure 1 The FT-IR spectra of PA.

Figure 2 The FT-IR spectra of APEG (a), APEL (b), and AA–APEL–PA (c).

Figure 2 The FT-IR spectra of APEG (a), APEL (b), and AA–APEL–PA (c).

Figure 3 1H NMR spectra of PY (a) and PA (b).

Figure 3 1H NMR spectra of PY (a) and PA (b).

Figure 4 1H NMR spectra of APEG (a), APEL (b), and AA–APEL–PA (c).

Figure 4 1H NMR spectra of APEG (a), APEL (b), and AA–APEL–PA (c).

Figure 5 Influence of mole ratio of AA:APEL on calcium phosphate inhibition of AA–APEL–PA.

Figure 5 Influence of mole ratio of AA:APEL on calcium phosphate inhibition of AA–APEL–PA.

Figure 6 Inhibition on calcium phosphate as a function of AA–APEL–PA dosage.

Figure 6 Inhibition on calcium phosphate as a function of AA–APEL–PA dosage.

Figure 7 Inhibition at a level of 6 mg/L AA–APEL–PA as a function of solution Ca2+ concentration (a), temperature (b), pH (c), and Fe2+ concentration (d).

Figure 7 Inhibition at a level of 6 mg/L AA–APEL–PA as a function of solution Ca2+ concentration (a), temperature (b), pH (c), and Fe2+ concentration (d).

Figure 8 Excitation and emission wavelength of PA (a) and AA–APEL–PA (b).

Figure 8 Excitation and emission wavelength of PA (a) and AA–APEL–PA (b).

Figure 9 Linearity of fluorescent intensity and concentration of AA–APEL–PA.

Figure 9 Linearity of fluorescent intensity and concentration of AA–APEL–PA.

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