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Journal of Sulfur Chemistry Volume 26, 2005 - Issue 4-5
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Original Articles

ZrCl4/NaI and ZrOCl2 · 8H2O/NaI as effective systems for reductive coupling of sulfonyl chlorides and chemoselective deoxygenation of sulfoxides

H. Firouzabadi Chemistry Department, College of Sciences, Shiraz University, Shiraz, 71454, IranCorrespondence[email protected]
,
N. Iranpoor Chemistry Department, College of Sciences, Shiraz University, Shiraz, 71454, IranCorrespondence[email protected]
&
M. Jafarpour Chemistry Department, College of Sciences, Shiraz University, Shiraz, 71454, Iran
Pages 313-324 | Received 14 Aug 2005, Published online: 19 Aug 2006
 
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Abstract

Zirconium tetrachloride/sodium iodide (ZrCl4/NaI) and ZrOCl2 · 8H2O/NaI conduct effective reductive coupling of sulfonyl chlorides to their corresponding disulfides and chemoselective reduction of sulfoxides to their thioethers in high yields.

Acknowledgements

We are grateful to Iran TWAS Chapter Based at ISMO and the Shiraz University Research Council for the support of this work.

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