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RESEARCH LETTERS

3-[(4-amino-2- methyl-5-pyrimidinyl) methyl]-5- (2-hydroxyethyl)-4-methyl thiazolium chloride hydrochloride as green corrosion inhibitor of copper in HNO3 solution and its adsorption characteristics

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Pages 273-279 | Received 06 Nov 2009, Accepted 10 Mar 2011, Published online: 03 Jun 2011

Figures & data

Figure 1.  Variation of weight loss with thiamine hydrochloride concentration for copper in 2.5 M HNO3 at 30°C.

Figure 1.  Variation of weight loss with thiamine hydrochloride concentration for copper in 2.5 M HNO3 at 30°C.

Table 1. Percentage inhibition efficiency, corrosion rate, and surface coverage of thiamine of thiamine hydrochloride on copper at 30°C 30 min immersion period.

Figure 2.  Variation of percentage inhibition efficiency of thiamine hydrochloride with immersion period.

Figure 2.  Variation of percentage inhibition efficiency of thiamine hydrochloride with immersion period.

Figure 3.  Langmuir adsorption plot for copper in 2.5 M HNO3 solution containing thiamine hydrochloride at 30°C.

Figure 3.  Langmuir adsorption plot for copper in 2.5 M HNO3 solution containing thiamine hydrochloride at 30°C.

Figure 4.  Variation of percentage inhibition efficiency of thiamine hydrochloride with temperature.

Figure 4.  Variation of percentage inhibition efficiency of thiamine hydrochloride with temperature.

Figure 5.  Plot of log (θ/1 – θ) versus 1/T at concentrations of 0.5, 1, and 2 mM thiamine hydrochloride.

Figure 5.  Plot of log (θ/1 – θ) versus 1/T at concentrations of 0.5, 1, and 2 mM thiamine hydrochloride.

Table 2. Heat of adsorption, Q ad and the correlation coefficients for thiamine hydrochloride on copper surface in 2.5 M HNO3.

Figure 6.  Arrhenius plots for copper in 2.5 M solution with and without thiamine hydrochloride.

Figure 6.  Arrhenius plots for copper in 2.5 M solution with and without thiamine hydrochloride.

Figure 7.  Errying plots for copper in 2.5 M solution with and without thiamine hydrochloride.

Figure 7.  Errying plots for copper in 2.5 M solution with and without thiamine hydrochloride.

Table 3. Corrosion activation parameters and the correlation coefficients for copper in 2.5 M HNO3 with and without thiamine hydrochloride.

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