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Research Article

In situ reinforcing of monomer casting nylon-6 with nylon fiber and the interface failure mechanism

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Pages 79-92 | Received 20 May 2021, Accepted 06 Jul 2021, Published online: 14 Jul 2021
 

ABSTRACT

Nylon fiber with identical structure with PA6 was firstly applied as reinforcing filler, and MC PA6/nylon fiber composites were in situ synthesized by introducing polyethylene glycol (PEG). Thus interfacial interaction, uniformity, and dispersion of composite were improved without settling of fibers in caprolactam during polymerization. Effect of nylon fiber content on polymerization kinetics was studied, and crystallization behavior and mechanical properties of composites were investigated, while nylon fiber-PEG showed reinforcing and toughening effect on matrix. Under stress, nylon fiber with skin-core structure was pulled out without interfacial debonding, resulting in ductile fracture with large deformation on fractured surface of composite.

Graphical abstract

Disclosure statement

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

The authors declare the following financial interests/personal relationships which may be considered as potential competing interests.

Additional information

Funding

This work was supported by Science and Technology Project of Sichuan Province [2019YFG0240].

Notes on contributors

Xiaotong Yin

Xiaotong Yin is currently a master degree candidate at Sichuan University. Her research work mainly focused on the preparation of monomer casting nylon-6 with high performances.

Xiaowen Zhao

Xiaowen Zhao is an associate professor of Sichuan University. She is mainly engaged in the synthesis, preparation, processing and structural characterization of polymer-based blends or composites.

Lin Ye

Lin Ye is a professor of Sichuan University. She is mainly engaged in the research and development of engineering plastics, water-based and environment-friendly polymer materials.

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