Advanced search
Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 20
Submit an article Journal homepage
131
Views
16
CrossRef citations to date
0
Altmetric
Original Articles

PALLADIUM-CATALYZED DICARBONYLATION OF TERMINAL ACETYLENES: A NEW METHOD FOR SELECTIVE SYNTHESIS OF UNSATURATED DIESTERS AND MALEIC ANHYDRIDES

Jinheng Li Chinese Academy of Sciences, LCLC, Guangzhou Institute of Chemistry, P.O. Box 1122, Guangzhou, 510 650, P. R. China
,
Huanfeng Jiang Chinese Academy of Sciences, LCLC, Guangzhou Institute of Chemistry, P.O. Box 1122, Guangzhou, 510 650, P. R. China
&
Mingcai Chen Chinese Academy of Sciences, LCLC, Guangzhou Institute of Chemistry, P.O. Box 1122, Guangzhou, 510 650, P. R. China
Pages 3131-3134 | Received 20 Dec 2000, Published online: 16 Aug 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

Maleate diesters and maleic anhydrides can be synthesized respectively by using different type of alcohol in the palladium catalyzed dicarbonylation of terminal acetylene. In primary or second aliphatic alcohols, only α,β-unsaturated diesters were yielded. In tert-BuOH, maleic anhydrides were selectively synthesized.

ACKNOWLEDGMENT

We thank the National Natural Science Foundation of China for financial support (No. 29772036 and 29872039).

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 422.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.