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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 1
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Original Articles

CATALYTIC OLEFIN EPOXIDATION WITH MOLECULAR OXYGEN OVER SUPPORTED AMIDATE-BRIDGED PLATINUM BLUE COMPLEXES

, &
Pages 17-22 | Received 20 Oct 2000, Published online: 21 Aug 2006
 

ABSTRACT

The platinum complexes, [Pt4(NH3)8((CH3)3CCONH)4]-(NO3)5 and [Pt2(NH3)4((CH3)3CCONH)2](NO3)4, supported on a surface of silica gel, Al2O3, activated carbon, and poly-(4-vinylpyridine) are active heterogeneous catalysts for the liquid phase epoxidation of various olefins under 1 atm of dioxygen in the presence of isobutyraldehyde.

Acknowledgments

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