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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 6
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Original Articles

INDIUM-MEDIATED ALLYLATION OF ACYL CYANIDES IN AQUEOUS MEDIA: A CONVENIENT SYNTHESIS OF β,γ-UNSATURATED KETONES

Byung Woo Yoo Department of Chemistry, Korea University, Chochiwon, Chungnam, 339-700, Korea
,
Kwang Hyun Choi Department of Chemistry, Korea University, Chochiwon, Chungnam, 339-700, Korea
,
Sung Jae Lee Department of Chemistry, Korea University, Chochiwon, Chungnam, 339-700, Korea
,
Ghil Soo Nam Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul, 130-650, Korea
,
Kwan Young Chang Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul, 130-650, Korea
,
Sung Hoon Kim Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul, 130-650, Korea
&
Joong Hyup Kim Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul, 130-650, Korea
 show all
Pages 839-846 | Received 13 Nov 2000, Published online: 16 Aug 2006
 
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ABSTRACT

The indium-mediated allylation reaction of acyl cyanides with allyl halides in aqueous media afforded a variety of β,γ-unsaturated ketones in moderate to good yields under mild and neutral conditions.

ACKNOWLEDGMENTS

This work was financially supported by Korea Institute of Science and Technology (2E16800) and partially by Korea University.

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