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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 8
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Original Articles

Selective Oxidation of Benzylic Substrates to Their Corresponding Carbonyl Compounds with 3,6-Bis(Triphenylphosphonium)cyclohexene Peroxodisulfate

Rashid Badri Department of Chemistry, Chamran University, Ahvaz, Iran
&
Mousa Soleymani Department of Chemistry, Chamran University, Ahvaz, Iran
Pages 1325-1332 | Received 17 Feb 2002, Published online: 15 Aug 2006
 
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Abstract

3,6-Bis(triphenylphosphonium)cyclohexene peroxodisulfate (BTPCP) was found to be a highly effective and selective oxidant for the conversion of benzyl monohalides, nitrils, and amines to their corresponding carbonyl compounds under mild and neutral conditions.

Acknowledgment

The authors thank Chamran University for financial support of this work.

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