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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 11
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Original Articles

Cycloaddition Reaction of Epoxides with Various Alkenes Under Microwave Irradiation

Ghania Bentabed Institut de Chimie, Université, Oran Es-Senia, Algérie
,
Aicha Derdour Institut de Chimie, Université, Oran Es-Senia, Algérie
&
Hadj Benhaoua Institut de Chimie, Université, Oran Es-Senia, Algérie; Université de Rennes I. Laboratoire de Synthèse et Electrosynthèse Organiques 3, Rennes, FranceCorrespondence[email protected]
Pages 1861-1866 | Received 20 Sep 2002, Published online: 17 Aug 2006
 
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Abstract

The reactivity of gem-dicyano epoxides with various alkenes is studies in solvent free conditions, and in homogeneous solution, under microwave irradiation. Microwave heating of these substrates in solvent, yields carbonyl ylides which give 1-3-dipolar cycloaddition.

Acknowledgments

We wish to thank Pr. J. Hamelin, Université de Rennes I, France, for technical support and fruitful discussions.

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