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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 13
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Original Articles

A Facile Synthesis of 2-Aroylindoles by the Oxidation of 2-Arylmethylindoles Using Sarett Reagent

Nagappan Arumugam R & D Department, Amrutanjan Ltd., Chennai, India
&
Panayencheri C. Srinivasan Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai, IndiaCorrespondence[email protected]
Pages 2313-2320 | Received 15 Oct 2002, Published online: 17 Aug 2006
 
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Abstract

A facile synthesis of 2-aroylindoles by the oxidation of 3-substituted 2-arylmethylindoles using Sarett reagent has been reported. The phenylthio group at 3-position has been cleaved by Raney nickel.

Acknowledgments

The authors thank UGC-SAP for instrument grants to the Department of Organic chemistry, University of Madras, Amrutanjan Ltd. for providing lab facilities to NA, Prof. D. Velmurugan, Dept. of Biophysics and Crystallography, University of Madras for x-ray analysis of carboxilic acid derivative of 3a and Dr. R. Murugesan, RSIC, IIT, Chennai for mass spectra.

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